Combine and stir all the spices to create the Chipotle Seasoning Blend.
In a large Ziplock bag or large bowl, mix the vinegar, fresh minced garlic, olive oil and water to create the marinade.
Add the seasoning blend to the marinade. Stir or squeeze contents until blended together.
Add the chicken thighs to the marinade, tossing the chicken to ensure the meat is moistened and covered with the marinade.
Marinate in the refrigerator for at least 3 hours, and up to 6 hours. Remove chicken from refrigerator when ready to cook.
Heat Oven to 425 ℉. Line a baking sheet with foil.
On the Stovetop over Medium Heat, warm 2 tbsp Extra Virgin Olive Oil to a large pot or dutch oven.
Add chicken thighs one at a time to the hot pot, working in batches so that the chicken does not overlap and to avoid overcrowding the pot. Cook on the stovetop about 2-3 minutes per side, flipping when the chicken is noticeably browned. Remove from stovetop and place on prepared baking sheet.
Once all the chicken has been browned and placed on your baking sheet, finishing baking in the oven at 425℉ for 5 minutes.
Remove from oven and allow to rest for about 3 minutes to allow juices to redistribute.
Cut on a diagonal or in cubes and serve with your favorite burrito bowl toppings.